Antonino GULINO

Antonino Gulino Prof. Ordinario di Chimica Inorganica, (SSD) 03/B1  -  CHIM/03

Insegnamenti: Complementi di Chimica Inorganica e Laboratorio presso il CdL in Chimica Industriale; Chimica presso il CdL in Fisica.

Principali tematiche di ricerca:

1. Materiali funzionali
2. Architetture molecolari
3. Ossidi conduttori nanostrutturati

ORCID ID: 0000-0002-6850-3080

Indirizzo web Researchgate: https://www.researchgate.net/profile/Antonino_Gulino 

Antonino Gulino

ruolo: Professore ordinario

Settore scientifico-disciplinare: 03/B1  -  CHIM/03

Attività Scientifica

L’attività scientifica di Antonino Gulino è principalmente rivolta a settori inerenti la Chimica Inorganica dei Materiali e le Nanoscienze. In particolare si occupa di materiali funzionali, architetture molecolari, self-assembly, nanostrutture, ossidi conduttori, strutture elettroniche di composti inorganici. La sua attività scientifica è documentata da oltre 125 pubblicazioni su riviste ISI (h-index 32, fonte: Web of Science).

Collaborazioni Internazionali attive:

• University of Oxford, Oxford, UK (Profs: R. G. Egdell; R. Jacobs)
• Weizmann Institute of Science, Israel (Profs. van der Boom;  Rybtchinski; Weissman)
• University of Cambridge, UK (Prof. J. R. Nitschke)
• Heidelberg University, Germany (Prof. M. Zharnikov)
• Northwestern University, USA (Prof. P. Dutta)
• University of Delhi, India (Prof. S. K. Awasthi)
• South Asian University, India (Prof. R. D. Gupta)
• Banaras Hindu University, India (Prof L. Mishra)
• The Volcani Center, Bet-Dagan, Israele. (Dr. Elena Poverenov)

Soggiorni all’Estero per Attività Scientifica        

• Aprile 2015 visiting professor, Trinity College, Oxford, UK.
• Settembre 2009 Chairman al 5 ° Corea-Italia Inorganic Chemistry Symposium, Kyungju POSTECH, Pohang, Corea del Sud.
• Marzo 2006; Maggio 2007; Giugno - Settembre 2007; Giugno - Settembre 2008;, Maggio 2014,  visiting professor Weizmann Institute of Science, Rehovot, Israele.
• 1993-1994, visiting professor, Inorganic Chemistry Laboratory, University of Oxford, England.

Recenti Riconoscimenti Scientifici Internazionali

• 2016  Cover, Hot Paper e Cover Profile su Chemistry, A Eur. J.
• 2014  Cover su Chem. Commun.
• 2014 Cover e e Cover Profile su Eur. J. Inorg. Chem.
• 2014  Analitycal and Bioanalitycal Chemistry Top 10 most cited in 2013.
• 2013  Highlight su RSC Chemistry World.
• 2013  Highlight su Le Scienze
• 2013  Cover su Analytical Methods
• 2009  Flyer di Chem. Commun
• 2010  Highlight su Angew. Chem.

Recenti Incarichi Internazionali per la valutazione di progetti di ricerca

• 2016 Referee Internazionale per l’FWO, Belgio.
• 2015 Esperto Valutatore per l’Accademia delle Scienze della Repubblica Ceca.
• 2011 Referee Internazionale per l’Austrian Science Fund (FWF)
• 2009 Referee Internazionale per la Binational Science Foundation (BSF).
• 2008 Referee Internazionale per la German - Israeli Foundation (G.I.F).

Attività didattica

• Complementi di Chimica Inorganica (triennale in Chimica Industriale),
• Chimica (Triennale in Fisica).

Pubblicazioni degli ultimi 6 anni di Antonino Gulino  (ORCID ID: 0000-0002-6850-3080)

127.     M. Cantarella, A. Di Mauro, A. Gulino, L. Spitaleri, V. Privitera, G. Impellizzeri

            Selective photodegradation of paracetamol by molecularly imprinted ZnO nanonuts.

            Applied Catalysis B: environmental, 2018, accepted.

126.     A. Contino, G. Maccarrone, L. Spitaleri, L. Torrisi, G. Nicotra, A. Gulino.

            One Pot Synthesis of Au ZnO Core-Shell Nanoparticles with a Unique Capping and Reducing Agent During the Au NPs Formation.

Eur. J. Inorg. Chem. 2018, Accepted.

125.     M. Zimbone, G. Cacciato, M. Boutinguiza, A. Gulino, M. Cantarella, V. Privitera, M. G. Grimaldi.

            Hydrogenated black-TiO_x: a Facile and Scalable Synthesis for Environmental Water Purification.

            Catalysis Today, 2018, In press.

            https://doi.org/10.1016/j.cattod.2018.03.040

   124.     H. Keisar, G. de Ruiter, A. H. Velders, P. Milko, A. Gulino, G. Evmenenko, L.  J. W. Shimon, Y. Diskin-Posner, M. Lahav, and M. E. van der Boom

            Sorting of Molecular Building Blocks from Solution to Surface.

            J. Am. Chem. Soc. 2018,

            DOI: 10.1021/jacs.8b02968

123.     R. Fiorenza, S. Sciré, A. Gulino, L. Spitaleri

            Ru-Pd bimetallic catalysts supported on CeO₂-MnO_X oxides as efficient systems for H₂ purification through CO preferential oxidation.

            Catalysts, 2018, 8, 203.

            DOI:10.3390/catal8050203

SCOPUS: 2-s2.0-85030452757

WOS:

122.     A. Contino, G. Maccarrone, M. E. Fragalà, L. Spitaleri, A. Gulino

Conjugated Gold-Porphyrin Monolayers Assembled on Inorganic Surfaces.

Chem. Eur. J. 2017, 23, 14937 – 14943.

DOI: 10.1002/chem.201703523

SCOPUS: 2-s2.0-85030452757

WOS: 000413337400032

 

121.    S. Wang, Y. Yu, R. Li, G. Feng, Z. Wu, G. Compagnini, A. Gulino, Z. Feng, A. Hu.

High-performance stacked in-plane supercapacitors and supercapacitor array fabricated by femtosecond laser 3D direct writing on flexible polyimide sheets.

Electrochimica Acta, 2017, 241, 153–161.

DOI: 10.1016/j.electacta.2017.04.138

SCOPUS: 2-s2.0-85018346820

WOS:000403026700015

 

120.    S. Millesi, M. R. Catalano, G. Impellizzeri, I. Crupi, G. Malandrino, F. Priolo, A. Gulino

Sb-Implanted p-Type ZnO Ultra-Thin Films.

Materials Science in Semiconductor Processing, 2017, 69, 32-35.

DOI: 10.1016/j.mssp.2016.12.025

SCOPUS: 2-s2.0-85009471603

WOS:000407601600008

 

119.    P. Mineo, A. Abbadessa, A. Mazzaglia, A. Gulino, V. Villari, N. Micali, S. Millesi, C. Satriano and E. Scamporrino.

Gold nanoparticles functionalized with PEGylate uncharged porphyrins.

Dyes and Pigments, 2017, 141, 225-234.

DOI:10.1016/j.dyepig.2017.02.018

SCOPUS: 2-s2.0-85013752135

WOS: 000399852700027

 

118.    A. Di Mauro, M. Cantarella, G. Nicotra, G. Pellegrino, A. Gulino, M. V. Brundo, V. Privitera and G. Impellizzeri

Novel synthesis of ZnO/PMMA composites for photocatalytic applications.

Scientific Reports, 2017, 7:40895, 1-13.

DOI:10.1038/srep40895       

SCOPUS: 2-s2.0-85010031133

WOS:000392189600001

 

117.    A. K. Srivastava, A. K. Singh, N. Kumari, A. Gulino, A. Speghini, R. Nagarajan, L. Mishra

Pyridyl substituted 4-(1,3-Dioxo-1H,3H-benzo[de]isoquinolin-2-ylmethyl)-benzamides with aggregation anhanced amission and multi-stimuli-responsive propeties.

J. Lumin. 2017, 182, 274-282.

DOI: 10.1016/j.jlumin.2016.10.042

SCOPUS: 2-s2.0-84995494149

WOS:000390510300041

 

116.    G. Trusso Sfrazzetto, S. Millesi, A. Pappalardo, G. Tomaselli, F. Ballistreri, M. R. Toscano, I. Fragalà and A. Gulino.

Nerve Gas Simulant Sensing by an Uranyl-Salen Monolayer Covalently Anchored on Quartz Substrates.

Chem. Eur. J. 2017, 23, 1576-1583.

DOI: 10.1002/chem.201602292

SCOPUS: 2-s2.0-85011421265

WOS:000395754200017

 

115b.    M. Schilirò, A. Contino, S. Millesi, G. Maccarrone and A. Gulino

Communication between Discrete Nanostructures Triggered by a Fine Tuning of an External Stimulus.

Chem. Eur. J. 2016, 22, COVER PICTURE,

DOI: 10.1002/chem.201603015

SCOPUS: 2-s2.0-84985032722

 

115a.    M. Schilirò, A. Contino, S. Millesi, G. Maccarrone and A. Gulino

Communication between Discrete Nanostructures Triggered by a Fine Tuning of an External Stimulus.HOT PAPER

Chem. Eur. J. 2016, 22, 13083 – 13088.

DOI: 10.1002/chem.201602262.

SCOPUS: 2-s2.0-84979632796

WOS: 000383763200021

 

114.    M. Schilirò, A. Contino, S. Millesi, G. Maccarrone and A. Gulino

Communication between Discrete Nanostructures Triggered by Fine Tuning of an External Stimulus.

Chem. Eur. J. 2016, 22, 12949. COVER PROFILE

DOI: 10.1002/chem.201603014.

SCOPUS: 2-s2.0-84979747867

WOS:

 

113.    M. Zimbone, G. Cacciato, R. Sanz, R.Carles, A. Gulino, V. Privitera, M. G. Grimaldi

Black TiOx photocatalyst obtained by laser irradiation in water.

Catal. Commun,  2016, 84, 11–15.

DOI.org/10.1016/j.catcom.2016.05.024

SCOPUS: 2-s2.0-84979295311

WOS: 000381534300003

 

112.    S. Scirè, R. Fiorenza, A. Gulino, A. Cristaldi, P. M. Riccobene

Selective oxidation of CO in H₂-rich stream over ZSM5 zeolites supported Ru catalysts: an investigation on the role of the support and the Ru particle size

Applied Catalysis A: General 2016, 520, 82–91.

doi.org/10.1016/j.apcata.2016.04.011

SCOPUS: 2-s2.0-84964354519

WOS:000378369400010

 

111.    A. Gulino

Reply to the ‘Comment on “A photoelectron spectroscopy study of lava stones” by M. Zappia and A. Nicoletti, Anal. Methods, 2016, 8, DOI: 10.1039/c3ay41326h.

Analytical. Methods, , 2016, 8, 3849.

DOI: 10.1039/C4AY01109K

SCOPUS: 2-s2.0-84973596270

WOS:000375577600025

 

110.    S. Millesi, M. Schilirò, F. Greco, I. Crupi, G. Impellizzeri, F. Priolo, R.G. Egdell, A. Gulino

Nanostructured CdO Thin Films for Water Treatments.

Materials Science in Semiconductor Processing, 2016, 42, 85-88.

DOI: 10.1016/j.mssp.2015.08.005

SCOPUS: 2-s2.0-84939825165

WOS: 000367638100017

 

109.     D. A. Cristaldi, S. Millesi, P. Mineo and A. Gulino

            A Chemical Address for the Morse Code

            J. Lumin, 2016, 169, 348–352.

            DOI: 10.1016/j.jlumin.2015.10.004

            SCOPUS:2-s2.0-84944755317

            WOS: 000365604700053

 

108.     S. Millesi, R. Lo Nigro, M. Pedroni, A. Speghini, A. Gulino

            Photoexcited Porphyrins Functionalizing TiO₂ and SnO₂ Nanocrystals.

            J. Phys. Chem. C, 2015, 119, 23743−23751.

            DOI: 10.1021/acs.jpcc.5b06574

            SCOPUS:2-s2.0-84944407020

            WOS: 000363068400051

 

107.     A. Kumar, M. Chhatwal,  D. A. Cristaldi, S. K. Awasthi, R. D. Gupta, A. Gulino

            Chromogenic Homo-Dinuclear Ruthenium(II) Monolayer as a Tunable Molecular Memory Module for Multibit Information Storage.

            J Phys. Chem. C, 2015, 119, 5138-5145.

            DOI: 10.1021/jp5124629

            SCOPUS:2-s2.0-84924148372

            WOS: 000350840700079

 

106.     E. Khaskin, T. Fadida, Y. Kroupitsky, M. Shemesh, D. A. Cristaldi, A. Gulino, E. Poverenov

            A contact active bactericidal stainless steel via a sustainable process utilizing electrodeposition and covalent attachment in water.

            Green Chemistry, 2015,17, 2344-2347.

            DOI: 10.1039/C4GC02326A

            SCOPUS: 2-s2.0-84928011785

            WOS: 000352724200036

 

105      S. Millesi, G. Maccarrone, A. Gulino

            Solid nanoarchitecture – Cu(II) solution: dynamics of the chemical communication.

            PhysChemChemPhys., 2015, 17, 6612 – 6617.

            DOI:10.1039/C5CP00169B

            SCOPUS: 2-s2.0-84923239514

            WOS: 000351435300051

 

104.     F. Pappalardo, D. A. Cristaldi, I. L. Fragalà, S. Millesi, M. De Bonis, A. Gulino

            Spectroscopic and Morphological Characterization of Inflow Cannulas of Left Ventricular Assist Devices.

            ASAIO Journal (American Society for Artificial Internal Organs: 1992), 2015, 61(2), 150-155.

            DOI:10.1097/MAT.0000000000000169

            SCOPUS: 2-s2.0-84912000686

            WOS: 000352853600007

            PubMed ID:25396275

            NLM Unique ID:9204109

 

103.     K. Barbera, P. Lanzafame, A. Pistone, S. Millesi, G. Malandrino, A. Gulino, S. Perathoner, G. Centi

            The role of oxide location in HMF etherification with ethanol over sulfated ZrO₂ supported on SBA-15.

            Journal of Catalysis, 2015, 323, 19–32

            DOI: 10.1016/j.jcat.2014.12.001

            SCOPUS: 2-s2.0-84921681204

            WOS:000350777600003

 

102      G. Trusso Sfrazzetto, S. Millesi, A. Pappalardo, R. M. Toscano, F. P. Ballistreri, G. A. Tomaselli, A. Gulino

            Olefin Epoxidation by a (salen)Mn(III) Oxene Catalyst Covalently Grafted on Glass Beads.

            Catal. Sci. Technol., 2015, 5, 673–679.

            DOI: 10.1039/C4CY00831F

            SCOPUS: 2-s2.0-84927802901

            WOS:000348937900006

 

101.     D. A. Cristaldi, S. Millesi,  I. Crupi, G. Impellizzeri, F. Priolo, R. M. J. Jacobs, R. G. Egdell and A. Gulino

            Structural, electronic, and electrical properties of an Undoped n-Type CdO thin film with high electron concentration.

            J Phys. Chem. C, 2014, 118(27), 15019-15026.

            DOI:10.1021/jp5040085

            SCOPUS: 2-s2.0-84904336357

            WOS:000338980400036

 

100.     S. Millesi, A. Gulino

            Optical properties of porphyrin–Eu-b-diketonate supramolecular nanostructures.

            J. Mater. Chem. C 2014, 2 (29), 5924 – 5930.

            DOI:10.1039/c4tc00439f

            SCOPUS:2-s2.0-84903973577

            WOS:000339396700025

 

99.       M. Morozov, L. Motiei, J. Choudhury, A. Gulino, M. Lahav, M. E. van der Boom

            Interfacial Mass Transfer by Controlled Multilayer Disassembly.

            Chem. Commun. 2014, 50(60), 8154-8156.

            DOI:10.1039/c4cc00495g

            SCOPUS:2-s2.0-84903698880

            WOS:000339172000015

 

98.       R. Kaminker, M. Lahav, M. Altman, G. Evmenenko, P. Dutta, A. Gulino, M. E. van der Boom

            Surface-Confined Core-Shell Structures based on Gold Nanoparticles and Metal-Organic Networks.

            Chem. Commun. 2014, 50, 4635-4638.

            DOI:10.1039/C3CC47865C

            WOS:000334599800028

            SCOPUS:2-s2.0-84898729842

 

97.       A. Kumar, M. Chhatwal, P. C. Mondal, V. Singh, D. A. Cristaldi, R. D. Gupta, A. Gulino

            Ternary Memory Module Using Low-Voltage Control over Optical Properties of Metal-Polypyridyl Monolayers.

            Chem. Commun. 2014, 50 (29), 3783-3785.

            DOI:10.1039/C4CC00388H

            WOS:000333037000002

            SCOPUS:2-s2.0-84896278667

 

96.       T. Gupta,   A. Gulino,   L. Mishra,   P. K. Yadav,   A. Kumar,   A. K Singh,  N. K Singh  

            Azobenzamide-based proteomorphous objects as a light/pH-induced photoswitchable module.

            RSC Advances, 2014, 4, 7174-7177.

            DOI:  10.1039/C3RA43576H

            SCOPUS: 2-s2.0-84892645404

            WOS:000329992200044 

 

95.       A. Gulino, F. Lupo, D. A. Cristaldi, S. Pappalardo, C. Capici, G. Gattuso, A. Notti, M. F. Parisi         

            A Viable Route for Lithium ion detection.

            Eur. J. Inorg. Chem. 2014, 2014(3), 414. COVER PROFILE

            DOI:10.1002/ejic.201301613

            SCOPUS

            WOS

 

94.       A. Gulino, F. Lupo, D. A. Cristaldi, S. Pappalardo, C. Capici, G. Gattuso, A. Notti, M. F. Parisi         

            A Viable Route for Lithium ion detection.

            Eur. J. Inorg. Chem. 2014, 414, 442–449.

            DOI: 10.1002/ejic.201301213

            SCOPUS: 2-s2.0-84892949144

            WOS:000329999400004

           

93        R. Kaminker, X. R. von Hatten, M. Lahav, F. Lupo, A. Gulino, G. Evmenenko, P. Dutta, C. Browne,  J. R. Nitschke, M. E. van der Boom

            Assembly of Surface-Confined Homochiral Helicates: Chiral Discrimination of DOPA

            and Unidirectional Charge Transfer.

            J. Am. Chem. Soc. 2013, 135, 17052−17059.

            DOI: 10.1021/ja4077205

            SCOPUS: 2-s2.0-84887730770

            WOS:000327103600047

 

92.       G. de Ruiter, M. Lahav, G. Evemenko, P. Dutta, D. A. Cristaldi, A. Gulino, M. E. van der Boom

            Composite Molecular Assemblies: Nanoscale Structural Control and Spectroelectrochemical Diversity.

            J. Am. Chem. Soc. 2013, 135, 16533-16544.

            DOI: 10.1021/ja407659z

            SCOPUS: 2-s2.0-84887660311

            WOS:000326774300052

 

91.       E. Poverenov, M. Shemesh, A. Gulino, D. A. Cristaldi, V. Zakin, T Yefremov, R. Granit

            Durable Contact Active Antimicrobial Materials Formed by a One-Step Covalent Modification

            of Polyvinyl Alcohol, Cellulose and Glass Surfaces.

            Colloids-and-Surfaces-B-Biointerfaces, 2013, 112, 356-361.

            DOI: 10.1016/j.colsurfb.2013.07.032

            SCOPUS:2-s2.0-84883674811

            WOS:000328593100050

 

90.       D. A. Cristaldi, S. Millesi, P. Mineo, A. Gulino

            Europium Complex Covalently Grafted on Si(100) Surfaces, Engineered with Covalent Polystyrene Nanostructures.

            J. Phys. Chem. C, 2013, 117, 16213-16220.

            DOI:10.1021/jp403070y

            SCOPUS:2-s2.0-84881460762

            WOS:000323082300042

 

89.       M. R. Catalano, R. G. Toro, A. Gulino, G. Malandrino

            Perovskite LaCO₃ thin films on single crystal substrates: MOCVD growth

            and characterization.

            Surf. Coat. Technol. 2013, 230, 174-179.

            DOI:10.1016/j.surfcoat.2013.06.068

            SCOPUS: 2-s2.0-84881315386

            WOS:000323855700027

 

88.       D. A. Cristaldi, A. Motta, S. Millesi, T. Gupta, M. Chhatwalb, A. Gulino

            Long Range Order in Si(100) Surfaces Engineered with Porphyrin Nanostructures

            J. Mater. Chem. C. 2013, 1, 4979-4984.

            DOI:10.1039/C3TC30628C.

            SCOPUS: 2-s2.0-84883243594

            WOS:000322254100022

 

87.       A. Gulino, I. L. Fragalà, F. Lupo, G. Malandrino, A. Motta, A. Colombo, C. Dragonetti, S. Righetto, D. Roberto, R. Ugo, F. Demartin, I. Ledoux-Rak, A. Singh

            Fascinating Role of the Number of f Electrons in Dipolar and Octupolar Contributions to Quadratic Hyperpolarizability of

            trinuclear lanthanides-biscopper Schiff base complexes.

            Inorg. Chem. 2013, 52, 7550-7556.

            DOI:10.1021/IC400558B

            SCOPUS:2-s2.0-84879749623

            WOS:000321471800030

  

86.       D. A. Cristaldi, C. G. Fortuna, A. Gulino

            A Photoelectron Spectroscopy Study of Lava Stones

            Analytical. Methods, 2013, 5, 3458-3462.

            DOI:10.1039/C3AY40136G

            SCOPUS:2-s2.0-84879751640

            WOS:000321011900004

 

85.       D. A. Cristaldi, A. Gulino

            Functionalization of SnO₂ Crystals with a Covaleny Assembled Porphyrin Monolayer.

            ChemSusChem,  2013, 6, 1031-1036.

            DOI: 10.1002/cssc.201300149.

            SCOPUS:2-s2.0-84878619319

            WOS:000319828000013

 

84.       P. G. Mineo, D. A. Cristaldi, A. Motta, T. Gupta, A. Gulino

            Covalent Poly(methyl methacrylate) Nanostructures on Functionalized Si(100) Surfaces.

            RSC Adv., 2013, 3, 1137-1144.

            DOI:10.1039/C2RA22327A

            SCOPUS: 2-s2.0-84871801440

            WOS:000312390000025

 

83.       A. Gulino

            Structural and Electronic Characterization of Self-Assembled Molecular Nanoarchitectures by X-ray Photoelectron Spectroscopy.

            Anal. Bioanal. Chem. 2013, 405, 1479-1495.

            DOI:10.1007/s00216-012-6394-8

            SCOPUS: 2-s2.0-84873737874

            WOS:000313960000005

 

• A.A. 2018/2019 - Chimica - 1 anno
  CHIMICA GENERALE ED INORGANICA I E LABORATORIO A - L
  
  
• A.A. 2017/2018 - Chimica industriale - 3 anno
  COMPLEMENTI DI CHIMICA INORGANICA E LABORATORIO
  
  
• A.A. 2016/2017 - Chimica industriale - 3 anno
  COMPLEMENTI DI CHIMICA INORGANICA
  
  
• A.A. 2015/2016 - Chimica industriale - 3 anno
  COMPLEMENTI DI CHIMICA INORGANICA

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• DIPARTIMENTO DI FISICA ED ASTRONOMIA
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L’attività scientifica di Antonino Gulino è principalmente rivolta a settori inerenti la Chimica Inorganica dei Materiali e le Nanoscienze. In particolare si occupa di materiali funzionali, architetture molecolari, self-assembly, nanostrutture, ossidi conduttori, strutture elettroniche di composti inorganici. La sua attività scientifica è documentata da oltre 125 pubblicazioni su riviste ISI (h-index 32, fonte: Web of Science).

Referente per l'Assicurazione Qualità del dipartimento di Scienze Chimiche