CHIMICA INORGANICA II E LABORATORIO
Academic Year 2019/2020 - 3° Year
Teaching Staff: Graziella VECCHIO
Credit Value: 6
Scientific field: CHIM/03 - General and inorganic chemistry
Taught classes: 28 hours
Laboratories: 24 hours
Term / Semester: 2°
Credit Value: 6
Scientific field: CHIM/03 - General and inorganic chemistry
Taught classes: 28 hours
Laboratories: 24 hours
Term / Semester: 2°
Learning Objectives
Knowledge of inorganic chemistry
Course Structure
In-room lectures and Lab experiences
Detailed Course Content
- Radiochemistry. Nuclear reactions Applications.
- d-Metal complexes: electronic structure and properties. Crystal field theory.
- Ligand field theory. Spectrochemical series of the ligands. Electronic spectra of coordination compounds. Orgel diagrams. Tanabe- Sugano diagrams. Magnetism.
- Thermodynamic stability of coordination compounds. Irving-Williams series.
- Ligand substitution reactions. Rates of ligand substitution. The classification of mechanisms. Redox reactions.
- Organometallic chemistry. Electron count preference. Ligands: Carbon monoxide, Hydrogen, Aromatic and aliphatic. Applications in organic synthesis.
- Bioinorganic chemistry. Role of the metal in biological systems.
Lab:
Synthesis of Co(en)3Cl3 and chiral resolution of enantiomers. UV-Vis spectra.
UV-Vis spectra of copper(II) and nickel (II) complexes with nitrogen ligands. Calculation of ∆o
Textbook Information
C.L. Miessler, D.A.Tarr Inorganic Chemistry, Pearson
P. Atkins Inorganic Chemistry, Oxford
C.E.Housecroft, A.G.Sharpe Inorganic Chemistry, Pearson
M. Halka, N. Brian Periodic Table of the Elements Transition metals, Facts on File