CHIMICA INORGANICA II E LABORATORIO
Academic Year 2016/2017 - 3° Year
Teaching Staff
Scientific field: CHIM/03 - General and inorganic chemistry
Taught classes: 40 hours
Term / Semester: 2°
- Inorganic chemistry II: Graziella VECCHIO
- Inorganic chemistry II: Graziella VECCHIO
Scientific field: CHIM/03 - General and inorganic chemistry
Taught classes: 40 hours
Term / Semester: 2°
Learning Objectives
- Inorganic chemistry II
Knowledge of inorganic chemistry
- Inorganic chemistry II
Knowledge of inorganic chemistry
Detailed Course Content
- Inorganic chemistry II
- Radiochemistry. Nuclear reactions Applications.
- d-Metal complexes: electronic structure and properties. Crystal field theory.
- Ligand field theory. Spectrochemical series of the ligands. Electronic spectra of coordination compounds. Orgel diagrams. Tanabe- Sugano diagrams. Magnetism.
- Thermodinamic stability of coordination compounds. Inrving-Williams series.
- Ligand substitution reactions. Rates of ligand substitution. The classification of mechanisms. Redox reactions.
- Organometallic chemistry. Electron count preference. Ligands: Carbon monoxide, Hydrogen, Aromatic and aliphatic. Applications in organic synthesis.
- Bioinorganic chemistry. Role of the metal in biological systems.
Lab:
Synthesis of Co(en)3Cl3 and chiral resolution of enantiomers. UV-Vis spectra.
UV-Vis spectra of copper(II) and nickel (II) complexes with nitrogen ligands. Calculation of ∆o
- Inorganic chemistry II
- Radiochemistry. Nuclear reactions Applications.
- d-Metal complexes: electronic structure and properties. Crystal field theory.
- Ligand field theory. Spectrochemical series of the ligands. Electronic spectra of coordination compounds. Orgel diagrams. Tanabe- Sugano diagrams. Magnetism.
- Thermodinamic stability of coordination compounds. Inrving-Williams series.
- Ligand substitution reactions. Rates of ligand substitution. The classification of mechanisms. Redox reactions.
- Organometallic chemistry. Electron count preference. Ligands: Carbon monoxide, Hydrogen, Aromatic and aliphatic. Applications in organic synthesis.
- Bioinorganic chemistry. Role of the metal in biological systems.
Lab:
Synthesis of Co(en)3Cl3 and chiral resolution of enantiomers. UV-Vis spectra.
UV-Vis spectra of copper(II) and nickel (II) complexes with nitrogen ligands. Calculation of ∆o
Textbook Information
- Inorganic chemistry II
C.L. Miessler, D.A.Tarr Chimica inorganica Piccin
P. Atkins Chimica Inorganica Zanichelli
C.E.Housecroft, A.G.Sharpe Inorganic Chemistry Pearson
- Inorganic chemistry II
C.L. Miessler, D.A.Tarr Chimica inorganica Piccin
P. Atkins Chimica Inorganica Zanichelli
C.E.Housecroft, A.G.Sharpe Inorganic Chemistry Pearson